Bright future for silicon

The Wiley-VCH journal ChemPhysChem issued an embargoed press release embargoed early on the morning of November 21, 2012, heralding "a bright future for silicon." Just eight hours later, they lifted the embargo, citing "early reporting" of the research by Brian Korgel of the University of Texas (Austin, TX) and colleagues.

Embargo breaks often indicate hot stories, and the headline hinted at an important step toward the elusive goal of efficient light emission from silicon. Yet the next line was more muted: "Ordered nanocrystal arrays may provide a new platform to study and tailor the light-emitting properties of silicon." What is the real story?

Silicon is a wonderful material for electronics, but its photonic uses have been hobbled by an indirect bandgap that makes it very hard for electrons dropping into the valence band to release their energy as photons. That leaves silicon far behind III-V compounds like gallium arsenide for LEDs and diode lasers. Yet silicon is far ahead of other semiconductors in electronics, and companies like Intel (Santa Clara, CA) want to integrate photonics into their integrated circuits.

So far they have demonstrated "silicon lasers" by optically pumping Raman lines in silicon and III-V diode laser chips bonded to silicon. Both were important advances. But neither met the real goal--electrically powered emitters based on silicon that could be integrated into standard semiconductor chip production processes.

In their ChemPhysChem paper, Korgel and colleagues take a different approach, tapping the bright luminescence produced by silicon quantum dots. They write that their major achievement is devising a chemical technique that causes self-assembly of "the first colloidal Si nanocrystal superlattices." Self-assembly is essential because individual dots are too small to fabricate by conventional photolithography, and transmission electron microscope images show the dots are closely spaced in regular face-centered-cubic arrangements (see photo).

TEM image silicon nanocrystals in the 111-oriented (c) and 112-oriented (d) plans, with depictions of the crystalline structures shown in insets. (Courtesy Yixuan Yu et al., ChemPhysChem, Wiley-VCH Verlag GmbH & Co. KGaA, http://dx.doi.org/10.1002/cphc.201200738 [2012]. Reproduced with permission)

The authors say that covalent bonds with the hydrocarbon solvent make the silicon-nanocrystal superlattices stable to 350 degrees Celsius, higher than other similar superlattices. That's encouraging news, because self-organized nanocrystals are a promising fresh approach to structuring silicon to emit light more efficiently. But so far electrical excitation--sought for integrated optoelectronics--has far to go to match the efficiency of optical excitation of isolated silicon quantum dots. So Korgel is understandably optimistic about having "a new playground for understanding and manipulating the properties of silicon in new and unique ways," and is appropriately cautious in not claiming silicon lasers are just around the corner.